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The first four are a great place to start, but I'd say that #5 and #6 are just as good (if not better) than the first four. They start to branch out into some of the more interesting European and Asian stuff, but keep a really good foothold in the ol' US of A. #5 has ESSENTIAL tracks by the Maggots, Dieter Meier, Hubble Bubble, Shit Dogs, Nubs and the Stalin. After #6 they start to get a little spotty, and they start to cover a lot of ground already covered on other comp series. Here's a few other comps and series really worth your time:
Smash the State 1-3 - A totally legit (ie. non-bootleg) comp series of Canadian KBD stuff. Very killer with great liner notes.
Deep In The Throat of Texas - Another legit comp of Texan KBD stuff.
Total Pop - Swedish KBD and powerpop stuff. But good like finding the LP. There were only 333 made.
Bloodstains - A KILLER series of region specific punk comps. The best ones are (in my opinion) all the USA ones (Texas, California, Midwest), Yugoslavia (No, REALLY), The Scandanavian ones (Finland, Denmark, Norway, Sweden), Europe and both "Bloodstains Across the World".
Where Birdmen Flew - an AMAZING Aussie collection.
Hate Your Neighbours - Cool New Zealand KBD stuff.
England Belongs to Me 1-3 - Great UK stuff that leans more towards the poppier side of KBD. These are GREAT. They're way better than the UK Bloodstains series.
Here's some good non-punk comps that are worth your time, too:
Killed By Glam - Exactly like it sounds. Rare UK glam shit from the 70s. Cool if you like that kinda thing.
Live to Ride, Ride To Live - Neat "New Wave of British Heavy Metal" comp. Most of it sounds like punk or oi with better musicianship and more polish. There's some really catchy shit on there.